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Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U(IV)–E–U(IV) cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange
We report the synthesis and characterisation of a family of diuranium(iv)-μ-chalcogenide complexes including a detailed examination of their electronic structures and magnetic behaviours. Treatment of [U(Tren(TIPS))] [1, Tren(TIPS) = N(CH(2)CH(2)NSiPr(i) (3))(3)] with Ph(3)PS, selenium or tellurium...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5628351/ https://www.ncbi.nlm.nih.gov/pubmed/28989654 http://dx.doi.org/10.1039/c7sc01998j |