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High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator
Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated reactions. We propose the deactivation pathways in...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5628575/ https://www.ncbi.nlm.nih.gov/pubmed/28989674 http://dx.doi.org/10.1039/c7sc02482g |