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Catalytic [2 + 2 + 2] cycloaddition with indium(iii)-activated formaldimines: a practical and selective access to hexahydropyrimidines and 1,3-diamines from alkenes

Catalytic [2 + 2 + 2] cycloaddition with imines has, for the first time, been developed as a practical and selective approach for direct construction of hexahydropyrimidine derivatives from various alkenes. With formaldimines as reagents and simple InCl(3) as the catalyst, this ionic [2 + 2 + 2] app...

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Detalles Bibliográficos
Autores principales: Zhou, Hui, Chaminda Lakmal, Hetti Handi, Baine, Jonathan M., Valle, Henry U., Xu, Xue, Cui, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5628582/
https://www.ncbi.nlm.nih.gov/pubmed/28989677
http://dx.doi.org/10.1039/c7sc02576a