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Are boat transition states likely to occur in Cope rearrangements? A DFT study of the biogenesis of germacranes
It has been proposed that elemanes are biogenetically formed from germacranes by Cope sigmatropic rearrangements. Normally, this reaction proceeds through a transition state with a chair conformation. However, the transformation of schkuhriolide (germacrane) into elemanschkuhriolide (elemane) may oc...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5629395/ https://www.ncbi.nlm.nih.gov/pubmed/29062416 http://dx.doi.org/10.3762/bjoc.13.192 |