1,3-Dibromo-5,5-dimethylhydantoin as promoter for glycosylations using thioglycosides

1,3-Dibromo-5,5-dimethylhydantoin (DBDMH), an inexpensive, non-toxic and stable reagent, is a competent activator of thioglycosides for glycosidic bond formation. Excellent yields were obtained when triflic acid (TfOH) or trimethylsilyl trifluoromethanesulfonate (TMSOTf) were employed as co-promoter...

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Detalles Bibliográficos
Autores principales: Xu, Fei-Fei, Pereira, Claney L, Seeberger, Peter H
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5629399/
https://www.ncbi.nlm.nih.gov/pubmed/29062419
http://dx.doi.org/10.3762/bjoc.13.195

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5629399/
https://www.ncbi.nlm.nih.gov/pubmed/29062419
http://dx.doi.org/10.3762/bjoc.13.195

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