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Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives

Charge-transfer (CT) π-complexes are formed between planar porphyrins and 1,4,5,8,9,12-hexaazatriphenylene (HAT) derivatives with large formation constants (e.g., 10(4) M(–1)), exhibiting broad CT absorption bands. The unusually large formation constants result from close face-to-face contact betwee...

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Detalles Bibliográficos
Autores principales: Aoki, Toru, Sakai, Hayato, Ohkubo, Kei, Sakanoue, Tomo, Takenobu, Taishi, Fukuzumi, Shunichi, Hasobe, Taku
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5630025/
https://www.ncbi.nlm.nih.gov/pubmed/29308129
http://dx.doi.org/10.1039/c4sc02787f