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Total syntheses of schilancidilactones A and B, schilancitrilactone A, and 20-epi-schilancitrilactone A via late-stage nickel-catalyzed cross coupling

The first total syntheses of schilancidilactones A and B, schilancitrilactone A, and 20-epi-schilancitrilactone A have been accomplished using a nickel-catalyzed cross coupling of alkyl bromide with vinyl stannane as the final step. The other key steps include late-stage C(sp(3))–H bromination, the...

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Detalles Bibliográficos
Autores principales: Wang, Hengtao, Zhang, Xiunan, Tang, Pingping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633787/
https://www.ncbi.nlm.nih.gov/pubmed/29081957
http://dx.doi.org/10.1039/c7sc03293e