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Two-Step, One-Pot Synthesis of Visible-Light-Responsive 6-Azopurines

[Image: see text] The first general two-step, one-pot synthetic route to 6-azopurines is presented. Microwave-assisted nucleophilic aromatic substitution of protected 6-chloropurines with hydrazines or hydrazides, followed by metal-free oxidation with oxygen, gives 6-azopurines in high to excellent...

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Detalles Bibliográficos
Autores principales: Kolarski, Dušan, Szymanski, Wiktor, Feringa, Ben L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5633830/
https://www.ncbi.nlm.nih.gov/pubmed/28891651
http://dx.doi.org/10.1021/acs.orglett.7b02361