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Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes
[Image: see text] We have developed a highly regioselective homogeneous gold(I)-catalyzed anti-hydrochlorination of unactivated alkynes at room temperature. We have overcome the incompatibility between conventional cationic gold catalysts and chloride by using a hydrogen-bonding activation of the Au...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5634393/ https://www.ncbi.nlm.nih.gov/pubmed/29034119 http://dx.doi.org/10.1021/acscatal.7b02567 |