Cargando…

Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes

[Image: see text] We have developed a highly regioselective homogeneous gold(I)-catalyzed anti-hydrochlorination of unactivated alkynes at room temperature. We have overcome the incompatibility between conventional cationic gold catalysts and chloride by using a hydrogen-bonding activation of the Au...

Descripción completa

Detalles Bibliográficos
Autores principales: Ebule, Rene, Liang, Shengzong, Hammond, Gerald B., Xu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5634393/
https://www.ncbi.nlm.nih.gov/pubmed/29034119
http://dx.doi.org/10.1021/acscatal.7b02567

Ejemplares similares