A unified photoredox-catalysis strategy for C(sp(3))–H hydroxylation and amidation using hypervalent iodine

We report a unified photoredox-catalysis strategy for both hydroxylation and amidation of tertiary and benzylic C–H bonds. Use of hydroxyl perfluorobenziodoxole (PFBl–OH) oxidant is critical for efficient tertiary C–H functionalization, likely due to the enhanced electrophilicity of the benziodoxole...

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Detalles Bibliográficos
Autores principales: Li, Guo-Xing, Morales-Rivera, Cristian A., Gao, Fang, Wang, Yaxin, He, Gang, Liu, Peng, Chen, Gong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5635418/
https://www.ncbi.nlm.nih.gov/pubmed/29081950
http://dx.doi.org/10.1039/c7sc02773g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5635418/
https://www.ncbi.nlm.nih.gov/pubmed/29081950
http://dx.doi.org/10.1039/c7sc02773g

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