A DFT calculation-inspired Rh(i)-catalyzed reaction via suppression of α-H shift in α-alkyldiazoacetates

Metal-associated carbenes from diazo compounds promote many useful chemistry transformations in modern organic chemistry. However, compared to α-aryldiazoacetate-derived carbenes (ArDCs), the synthetic application of α-alkyldiazoacetate-derived carbenes (AlDCs) is greatly limited due to intramolecul...

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Detalles Bibliográficos
Autores principales: Liu, Shunying, Jiang, Jun, Chen, Jianghui, Wei, Qinghua, Yao, Wenfeng, Xia, Fei, Hu, Wenhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5635810/
https://www.ncbi.nlm.nih.gov/pubmed/29081965
http://dx.doi.org/10.1039/c7sc00257b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5635810/
https://www.ncbi.nlm.nih.gov/pubmed/29081965
http://dx.doi.org/10.1039/c7sc00257b

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