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Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C–H bond insertion cascades

An unusual transition metal-free cascade reaction of alkynyl carbonazidates was discovered to form azasilacyclopentenes. Mild thermolysis afforded the products via a series of cyclizations, rearrangements, and an α-silyl C–H bond insertion (rather than the more common Wolff rearrangement, 1,2-shift,...

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Detalles Bibliográficos
Autores principales: Shih, Jiun-Le, Jansone-Popova, Santa, Huynh, Christopher, May, Jeremy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5637360/
https://www.ncbi.nlm.nih.gov/pubmed/29147544
http://dx.doi.org/10.1039/c7sc03130k