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Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C–H bond insertion cascades

An unusual transition metal-free cascade reaction of alkynyl carbonazidates was discovered to form azasilacyclopentenes. Mild thermolysis afforded the products via a series of cyclizations, rearrangements, and an α-silyl C–H bond insertion (rather than the more common Wolff rearrangement, 1,2-shift,...

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Detalles Bibliográficos
Autores principales:	Shih, Jiun-Le, Jansone-Popova, Santa, Huynh, Christopher, May, Jeremy A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5637360/ https://www.ncbi.nlm.nih.gov/pubmed/29147544 http://dx.doi.org/10.1039/c7sc03130k

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