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Room temperature C(sp(2))–H oxidative chlorination via photoredox catalysis
Photoredox catalysis has been developed to achieve oxidative C–H chlorination of aromatic compounds using NaCl as the chlorine source and Na(2)S(2)O(8) as the oxidant. The reactions occur at room temperature and exhibit exclusive selectivity for C(sp(2))–H bonds over C(sp(3))–H bonds. The method has...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5642143/ https://www.ncbi.nlm.nih.gov/pubmed/29147528 http://dx.doi.org/10.1039/c7sc03010j |