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A unified view to Brønsted acidity scales: do we need solvated protons?

The most comprehensive solvent acidity scale spanning 28 orders of magnitude of acidity was measured in the low-polarity solvent 1,2-dichloroethane (DCE). Its experimental core is linked to the unified acidity scale (pH(abs)) in an unprecedented and generalized approach only based on experimental va...

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Detalles Bibliográficos
Autores principales: Paenurk, Eno, Kaupmees, Karl, Himmel, Daniel, Kütt, Agnes, Kaljurand, Ivari, Koppel, Ilmar A., Krossing, Ingo, Leito, Ivo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5642146/
https://www.ncbi.nlm.nih.gov/pubmed/29147523
http://dx.doi.org/10.1039/c7sc01424d