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Mechanistic analysis of a copper-catalyzed C–H oxidative cyclization of carboxylic acids
We recently reported that carboxylic acids can be oxidized to lactone products by potassium persulfate and catalytic copper acetate. Here, we unravel the mechanism for this C–H functionalization reaction using desorption electrospray ionization, online electrospray ionization, and tandem mass spectr...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5642147/ https://www.ncbi.nlm.nih.gov/pubmed/29147527 http://dx.doi.org/10.1039/c7sc02240a |