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Mechanistic analysis of a copper-catalyzed C–H oxidative cyclization of carboxylic acids

We recently reported that carboxylic acids can be oxidized to lactone products by potassium persulfate and catalytic copper acetate. Here, we unravel the mechanism for this C–H functionalization reaction using desorption electrospray ionization, online electrospray ionization, and tandem mass spectr...

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Detalles Bibliográficos
Autores principales: Banerjee, Shibdas, Sathyamoorthi, Shyam, Du Bois, J., Zare, Richard N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5642147/
https://www.ncbi.nlm.nih.gov/pubmed/29147527
http://dx.doi.org/10.1039/c7sc02240a