Cargando…
Pd-catalyzed asymmetric allylic alkylations via C–H activation of N-allyl imines with glycinates
Herein is reported the first example of palladium-catalyzed asymmetric allylic alkylation (AAA) reactions involving 2-aza-π-allyl palladium intermediates. The 2-aza-π-allyl complex was generated via a novel mode of activation of N-allyl imines. Pd-catalyzed C(sp(3))–H activation of N-allyl imines an...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5643980/ https://www.ncbi.nlm.nih.gov/pubmed/29147506 http://dx.doi.org/10.1039/c7sc02899g |