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Gem-diol and Ketone Crystal-to-crystal Transition Phenomena

The generally thought unstable diol compound tetrazyl gem-diol (1, H(2)DTMdiol·2H(2)O), was firstly obtained in crystalline form by culturing the filtrate for ten days after acidification and filtration of aqueous solution of potassium salt of ketone (2, [K(HDTMone)·2H(2)O](n)). The stability of thi...

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Detalles Bibliográficos
Autores principales: Bo, Zhang, Sitong, Chen, Weiming, Guo, Weijing, Zhang, Lin, Wang, Li, Yang, Jianguo, Zhang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647396/
https://www.ncbi.nlm.nih.gov/pubmed/29044144
http://dx.doi.org/10.1038/s41598-017-13596-6