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Gem-diol and Ketone Crystal-to-crystal Transition Phenomena
The generally thought unstable diol compound tetrazyl gem-diol (1, H(2)DTMdiol·2H(2)O), was firstly obtained in crystalline form by culturing the filtrate for ten days after acidification and filtration of aqueous solution of potassium salt of ketone (2, [K(HDTMone)·2H(2)O](n)). The stability of thi...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647396/ https://www.ncbi.nlm.nih.gov/pubmed/29044144 http://dx.doi.org/10.1038/s41598-017-13596-6 |