Synthesis and reactivity of cyclo-tetra(stibinophosphonium) tetracations: redox and coordination chemistry of phosphine–antimony complexes

Reductive elimination of [R(3)PPR(3)](2+), [11(R)](2+), from the highly electrophilic Sb(III) centres in [(R(3)P)(3)Sb](3+), [8(R)](3+), gives Sb(I) containing cations [(R(3)P)Sb](1+), [9(R)](1+), which assemble into frameworks identified as cyclo-tetra(stibinophosphonium) tetracations, [(R(3)P)(4)S...

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Detalles Bibliográficos
Autores principales: Chitnis, Saurabh S., Robertson, Alasdair P. M., Burford, Neil, Weigand, Jan J., Fischer, Roland
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647858/
https://www.ncbi.nlm.nih.gov/pubmed/29308163
http://dx.doi.org/10.1039/c4sc03939d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647858/
https://www.ncbi.nlm.nih.gov/pubmed/29308163
http://dx.doi.org/10.1039/c4sc03939d

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