Cargando…
Synthesis and reactivity of cyclo-tetra(stibinophosphonium) tetracations: redox and coordination chemistry of phosphine–antimony complexes
Reductive elimination of [R(3)PPR(3)](2+), [11(R)](2+), from the highly electrophilic Sb(III) centres in [(R(3)P)(3)Sb](3+), [8(R)](3+), gives Sb(I) containing cations [(R(3)P)Sb](1+), [9(R)](1+), which assemble into frameworks identified as cyclo-tetra(stibinophosphonium) tetracations, [(R(3)P)(4)S...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5647858/ https://www.ncbi.nlm.nih.gov/pubmed/29308163 http://dx.doi.org/10.1039/c4sc03939d |