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Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds
The cyclopentadienyl molybdenum hydride compounds, Cp(R)Mo(PMe(3))(3–x)(CO)(x)H (Cp(R) = Cp, Cp*; x = 0, 1, 2 or 3), are catalysts for the dehydrogenation of formic acid, with the most active catalysts having the composition Cp(R)Mo(PMe(3))(2)(CO)H. The mechanism of the catalytic cycle is proposed t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5649328/ https://www.ncbi.nlm.nih.gov/pubmed/29308136 http://dx.doi.org/10.1039/c4sc03128h |