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Investigation of Melts of Polybutylcarbosilane Dendrimers by (1)H NMR Spectroscopy

Melts of polybutylcarbosilane (PBC) dendrimers from third (G3) up to sixth (G6) generations are investigated by (1)H NMR spectroscopy in a wide temperature range up to 493 K. At room temperature, NMR spectra of G3-G5 dendrimers exhibit resolved, solution-like spectra (“liquid” phase). In contrast, t...

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Detalles Bibliográficos
Autores principales: Matveev, Vladimir V., Markelov, Denis A., Dvinskikh, Sergey V., Shishkin, Andrei N., Tyutyukin, Konstantin V., Penkova, Anastasia V., Tatarinova, Elena A., Ignat’eva, Galina M., Milenin, Sergey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5651846/
https://www.ncbi.nlm.nih.gov/pubmed/29057955
http://dx.doi.org/10.1038/s41598-017-13743-z