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A heterobimetallic complex featuring a Ti–Co multiple bond and its application to the reductive coupling of ketones to alkenes
To explore metal–metal multiple bonds between first row transition metals, Ti/Co complexes supported by two phosphinoamide ligands have been synthesized and characterized. The Ti metalloligand Cl(2)Ti(XylNP(i)Pr(2))(2) (1) was treated with CoI(2) under reducing conditions, permitting isolation of th...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654242/ https://www.ncbi.nlm.nih.gov/pubmed/29142672 http://dx.doi.org/10.1039/c4sc03772c |