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Visible light photocatalytic reduction of aldehydes by Rh(iii)–H: a detailed mechanistic study
The chemoselective photoreduction of aldehydes in the presence of ketones was achieved using triethanolamine (TEOA) as sacrificial electron donor, proflavine (PF) as photocatalyst and [Cp*Rh(iii)(bpy)Cl]Cl (Rh(cat)) as mediator. The reducing agent, which reacts with the carbonyl group was found to b...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654342/ https://www.ncbi.nlm.nih.gov/pubmed/29142671 http://dx.doi.org/10.1039/c4sc03709j |