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Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay

Oxidation of hydrogen (H(2)) to protons and electrons for energy production in fuel cells is currently catalyzed by platinum, but its low abundance and high cost present drawbacks to widespread adoption. Precisely controlled proton removal from the active site is critical in hydrogenase enzymes in n...

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Detalles Bibliográficos
Autores principales: Darmon, Jonathan M., Kumar, Neeraj, Hulley, Elliott B., Weiss, Charles J., Raugei, Simone, Bullock, R. Morris, Helm, Monte L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5654417/
https://www.ncbi.nlm.nih.gov/pubmed/29142678
http://dx.doi.org/10.1039/c5sc00398a