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Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies

A transition-metal-free method has been developed for the boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with a silylborane in the presence of an alkali-metal alkoxide. The base-mediated boryl substitution of organohalides with a silylborane was recently reported to prov...

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Detalles Bibliográficos
Autores principales: Yamamoto, Eiji, Ukigai, Satoshi, Ito, Hajime
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656038/
https://www.ncbi.nlm.nih.gov/pubmed/29308171
http://dx.doi.org/10.1039/c5sc00384a