Electron‐Transfer and Hydride‐Transfer Pathways in the Stoltz–Grubbs Reducing System (KOtBu/Et(3)SiH)

Recent studies by Stoltz, Grubbs et al. have shown that triethylsilane and potassium tert‐butoxide react to form a highly attractive and versatile system that shows (reversible) silylation of arenes and heteroarenes as well as reductive cleavage of C−O bonds in aryl ethers and C−S bonds in aryl thio...

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Detalles Bibliográficos
Autores principales: Smith, Andrew J., Young, Allan, Rohrbach, Simon, O'Connor, Erin F., Allison, Mark, Wang, Hong‐Shuang, Poole, Darren L., Tuttle, Tell, Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656899/
https://www.ncbi.nlm.nih.gov/pubmed/28892585
http://dx.doi.org/10.1002/anie.201707914

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656899/
https://www.ncbi.nlm.nih.gov/pubmed/28892585
http://dx.doi.org/10.1002/anie.201707914

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