Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation

We herein showcase the ability of NHC‐coordinated dinuclear Ni(I)–Ni(I) complexes to override fundamental reactivity limits of mononuclear (NHC)Ni(0) catalysts in cross‐couplings. This is demonstrated with the development of a chemoselective trifluoromethylselenolation of aryl iodides catalyzed by a...

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Detalles Bibliográficos
Autores principales: Dürr, Alexander B., Fisher, Henry C., Kalvet, Indrek, Truong, Khai‐Nghi, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656904/
https://www.ncbi.nlm.nih.gov/pubmed/28795520
http://dx.doi.org/10.1002/anie.201706423

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5656904/
https://www.ncbi.nlm.nih.gov/pubmed/28795520
http://dx.doi.org/10.1002/anie.201706423

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