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Spying on the boron–boron triple bond using spin–spin coupling measured from (11)B solid-state NMR spectroscopy

There is currently tremendous interest in the previously documented example of a stable species exhibiting a boron–boron triple bond (Science, 2012, 336, 1420). Notably, it has recently been stated using arguments based on force constants that this diboryne may not, in reality, feature a boron–boron...

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Detalles Bibliográficos
Autores principales: Perras, Frédéric A., Ewing, William C., Dellermann, Theresa, Böhnke, Julian, Ullrich, Stefan, Schäfer, Thomas, Braunschweig, Holger, Bryce, David L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5657093/
https://www.ncbi.nlm.nih.gov/pubmed/29142694
http://dx.doi.org/10.1039/c5sc00644a