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Copper-catalyzed intermolecular C(sp(3))–H bond functionalization towards the synthesis of tertiary carbamates

We describe the development of an intermolecular unactivated C(sp(3))–H bond functionalization towards the direct synthesis of tertiary carbamates. The transformation proceeded using a readily available, abundant first-row transition metal catalyst (copper), and isocyanates as the source of the amid...

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Detalles Bibliográficos
Autores principales: Chikkade, Prasanna Kumara, Kuninobu, Yoichiro, Kanai, Motomu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5657409/
https://www.ncbi.nlm.nih.gov/pubmed/29142689
http://dx.doi.org/10.1039/c5sc00238a