Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles

An Ir-catalyzed asymmetric allylic alkylation of 3-substituted indoles is reported. The reaction provides indoline products containing multiple contiguous stereocenters with high site-, regio-, diastereo- and enantioselectivities in one step from a wide range of readily available starting materials....

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Detalles Bibliográficos
Autores principales: Zhang, Xiao, Liu, Wen-Bo, Tu, Hang-Fei, You, Shu-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5666512/
https://www.ncbi.nlm.nih.gov/pubmed/29142701
http://dx.doi.org/10.1039/c5sc01772f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5666512/
https://www.ncbi.nlm.nih.gov/pubmed/29142701
http://dx.doi.org/10.1039/c5sc01772f

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