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Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles
An Ir-catalyzed asymmetric allylic alkylation of 3-substituted indoles is reported. The reaction provides indoline products containing multiple contiguous stereocenters with high site-, regio-, diastereo- and enantioselectivities in one step from a wide range of readily available starting materials....
Autores principales: | Zhang, Xiao, Liu, Wen-Bo, Tu, Hang-Fei, You, Shu-Li |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5666512/ https://www.ncbi.nlm.nih.gov/pubmed/29142701 http://dx.doi.org/10.1039/c5sc01772f |
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