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NHC-catalysed benzoin condensation – is it all down to the Breslow intermediate?
The Breslow catalytic cycle describing the benzoin condensation promoted by N-heterocyclic carbenes (NHC) as proposed in the late 1950s has since then been tried by generations of physical organic chemists. Emphasis has been laid on proofing the existence of an enaminol like structure (Breslow inter...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5669215/ https://www.ncbi.nlm.nih.gov/pubmed/29449915 http://dx.doi.org/10.1039/c5sc02186c |