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Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization

A methodology for controlling aggregation in highly active and isoselective indium catalysts for the ring opening polymerization of racemic lactide is reported. A series of racemic and enantiopure dinuclear indium ethoxide complexes bearing salen ligands [(ONNO(R))InOEt](2) (R = Br, Me, admantyl, cu...

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Detalles Bibliográficos
Autores principales: Aluthge, D. C., Ahn, J. M., Mehrkhodavandi, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5669251/
https://www.ncbi.nlm.nih.gov/pubmed/29449930
http://dx.doi.org/10.1039/c5sc01584g