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All-metal aromatic cationic palladium triangles can mimic aromatic donor ligands with Lewis acidic cations
We present that cationic rings can act as donor ligands thanks to suitably delocalized metal–metal bonds. This could grant parent complexes with the peculiar properties of aromatic rings that are crafted with main group elements. We assembled Pd nuclei into equilateral mono-cationic triangles with u...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5672843/ https://www.ncbi.nlm.nih.gov/pubmed/29163890 http://dx.doi.org/10.1039/c7sc03475j |