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All-metal aromatic cationic palladium triangles can mimic aromatic donor ligands with Lewis acidic cations

We present that cationic rings can act as donor ligands thanks to suitably delocalized metal–metal bonds. This could grant parent complexes with the peculiar properties of aromatic rings that are crafted with main group elements. We assembled Pd nuclei into equilateral mono-cationic triangles with u...

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Detalles Bibliográficos
Autores principales: Wang, Yanlan, Monfredini, Anna, Deyris, Pierre-Alexandre, Blanchard, Florent, Derat, Etienne, Maestri, Giovanni, Malacria, Max
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5672843/
https://www.ncbi.nlm.nih.gov/pubmed/29163890
http://dx.doi.org/10.1039/c7sc03475j