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Trapping intermediate MLCT states in low-symmetry {Ru(bpy)} complexes
The picosecond excited state dynamics of [Ru(tpm)(bpy)(NCS)](+) (RubNCS(+) ) and [Ru(tpm)(bpy)(CN)](+) (RubCN(+) ) (tpm = tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine) have been analyzed by means of transient absorption measurements and spectroelectrochemistry. Emissive (3)MLCTs with (GS)HOMO(h(+...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5674176/ https://www.ncbi.nlm.nih.gov/pubmed/29163895 http://dx.doi.org/10.1039/c7sc02670f |