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Laboratory-scale photoredox catalysis using hydrated electrons sustainably generated with a single green laser

The ruthenium-tris-bipyridyl dication as catalyst combined with the ascorbate dianion as bioavailable sacrificial donor provides the first regenerative source of hydrated electrons for chemical syntheses on millimolar scales. This electron generator is operated simply by illumination with a frequenc...

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Detalles Bibliográficos
Autores principales: Naumann, Robert, Kerzig, Christoph, Goez, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5676201/
https://www.ncbi.nlm.nih.gov/pubmed/29163905
http://dx.doi.org/10.1039/c7sc03514d