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Laboratory-scale photoredox catalysis using hydrated electrons sustainably generated with a single green laser
The ruthenium-tris-bipyridyl dication as catalyst combined with the ascorbate dianion as bioavailable sacrificial donor provides the first regenerative source of hydrated electrons for chemical syntheses on millimolar scales. This electron generator is operated simply by illumination with a frequenc...
Autores principales: | Naumann, Robert, Kerzig, Christoph, Goez, Martin |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5676201/ https://www.ncbi.nlm.nih.gov/pubmed/29163905 http://dx.doi.org/10.1039/c7sc03514d |
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