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Photosensitizer-free visible light-mediated gold-catalysed cis-difunctionalization of silyl-substituted alkynes

A new photosensitizer-free visible light-mediated gold-catalysed cis-difunctionalization reaction is developed. The reaction was chemoselective towards silyl-substituted alkynes with excellent regioselectivity and good functional group compatibility, giving a series of silyl-substituted quinoliziniu...

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Detalles Bibliográficos
Autores principales: Deng, Jie-Ren, Chan, Wing-Cheung, Chun-Him Lai, Nathanael, Yang, Bin, Tsang, Chui-Shan, Chi-Bun Ko, Ben, Lai-Fung Chan, Sharon, Wong, Man-Kin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5676248/
https://www.ncbi.nlm.nih.gov/pubmed/29163908
http://dx.doi.org/10.1039/c7sc02294h