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Preparation of Labile Ni(+)(cyclam) Cations in the Gas Phase Using Electron-Transfer Reduction through Ion–Ion Recombination in an Ion Trap and Structural Characterization with Vibrational Spectroscopy
[Image: see text] Gas-phase ion chemistry methods that capture and characterize the degree of activation of small molecules in the active sites of homogeneous catalysts form a powerful new tool to unravel how ligand environments affect reactivity. A key roadblock in this development, however, is the...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5677246/ https://www.ncbi.nlm.nih.gov/pubmed/28961009 http://dx.doi.org/10.1021/acs.jpclett.7b02223 |