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Preparation of Labile Ni(+)(cyclam) Cations in the Gas Phase Using Electron-Transfer Reduction through Ion–Ion Recombination in an Ion Trap and Structural Characterization with Vibrational Spectroscopy

[Image: see text] Gas-phase ion chemistry methods that capture and characterize the degree of activation of small molecules in the active sites of homogeneous catalysts form a powerful new tool to unravel how ligand environments affect reactivity. A key roadblock in this development, however, is the...

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Detalles Bibliográficos
Autores principales: Munshi, Musleh U., Craig, Stephanie M., Berden, Giel, Martens, Jonathan, DeBlase, Andrew F., Foreman, David J., McLuckey, Scott A., Oomens, Jos, Johnson, Mark A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5677246/
https://www.ncbi.nlm.nih.gov/pubmed/28961009
http://dx.doi.org/10.1021/acs.jpclett.7b02223