Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination

[Image: see text] The alkynylation of naphthols takes place with total regiocontrol at the peri position of the hydroxyl group in the presence of [RuCl(2)(p-cymene)](2) as the catalyst. This reaction features high functional group tolerance. The related ortho-alkynylation of benzoic acids proceeds u...

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Detalles Bibliográficos
Autores principales: Tan, Eric, Konovalov, Andrey I., Fernández, Gabriela A., Dorel, Ruth, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5679662/
https://www.ncbi.nlm.nih.gov/pubmed/28976200
http://dx.doi.org/10.1021/acs.orglett.7b02655

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5679662/
https://www.ncbi.nlm.nih.gov/pubmed/28976200
http://dx.doi.org/10.1021/acs.orglett.7b02655

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