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Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination
[Image: see text] The alkynylation of naphthols takes place with total regiocontrol at the peri position of the hydroxyl group in the presence of [RuCl(2)(p-cymene)](2) as the catalyst. This reaction features high functional group tolerance. The related ortho-alkynylation of benzoic acids proceeds u...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5679662/ https://www.ncbi.nlm.nih.gov/pubmed/28976200 http://dx.doi.org/10.1021/acs.orglett.7b02655 |