Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C(2) Symmetric Digold Catalysts

[Image: see text] The enantioselective intermolecular gold(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C(2)-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enant...

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Detalles Bibliográficos
Autores principales: García-Morales, Cristina, Ranieri, Beatrice, Escofet, Imma, López-Suarez, Laura, Obradors, Carla, Konovalov, Andrey I., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5679663/
https://www.ncbi.nlm.nih.gov/pubmed/28922911
http://dx.doi.org/10.1021/jacs.7b07651

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5679663/
https://www.ncbi.nlm.nih.gov/pubmed/28922911
http://dx.doi.org/10.1021/jacs.7b07651

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