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A new approach to alkaloid-like systems: synthesis and crystal structure of 1-(2-acetyl-11-meth­oxy-5,6-di­hydro­[1,3]dioxolo[4,5-g]pyrrolo­[2,1-a]isoquinolin-1-yl)propan-2-one

The title compound, C(19)H(19)NO(5), (I), is the product of a domino reaction between cotarnine chloride and acetyl­acetylene catalysed by copper(I) iodide. The mol­ecule of (I) comprises a fused tetra­cyclic system containing two terminal five-membered rings (pyrrole and 1,3-dioxole) and two centra...

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Detalles Bibliográficos
Autores principales: Anh, Le Tuan, Titov, Alexander A., Samavati, Reza, Voskressensky, Leonid G., Varlamov, Alexey V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5683501/
https://www.ncbi.nlm.nih.gov/pubmed/29152361
http://dx.doi.org/10.1107/S2056989017015110