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Electron-deficient pyridinium salts/thiourea cooperative catalyzed O-glycosylation via activation of O-glycosyl trichloroacetimidate donors

The glycosylation of O-glycosyl trichloroacetimidate donors using a synergistic catalytic system of electron-deficient pyridinium salts/aryl thiourea derivatives at room temperature is demonstrated. The acidity of the adduct formed by the 1,2-addition of alcohol to the electron-deficient pyridinium...

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Detalles Bibliográficos
Autores principales: Shaw, Mukta, Kumar, Yogesh, Thakur, Rima, Kumar, Amit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5687052/
https://www.ncbi.nlm.nih.gov/pubmed/29181119
http://dx.doi.org/10.3762/bjoc.13.236