Tuning the Porphyrin Building Block in Self‐Assembled Cages for Branched‐Selective Hydroformylation of Propene

Unprecedented regioselectivity to the branched aldehyde product in the hydroformylation of propene was attained on embedding a rhodium complex in supramolecular assembly L2, formed by coordination‐driven self‐assembly of tris(meta‐pyridyl)phosphine and zinc(II) porpholactone. The design of cage L2 i...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Xiaowu, Nurttila, Sandra S., Dzik, Wojciech I., Becker, René, Rodgers, Jody, Reek, Joost N. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5697640/
https://www.ncbi.nlm.nih.gov/pubmed/28608592
http://dx.doi.org/10.1002/chem.201702113

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5697640/
https://www.ncbi.nlm.nih.gov/pubmed/28608592
http://dx.doi.org/10.1002/chem.201702113

Ejemplares similares