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Radical‐Based C−C Bond‐Forming Processes Enabled by the Photoexcitation of 4‐Alkyl‐1,4‐dihydropyridines

We report herein that 4‐alkyl‐1,4‐dihydropyridines (alkyl‐DHPs) can directly reach an electronically excited state upon light absorption and trigger the generation of C(sp(3))‐centered radicals without the need for an external photocatalyst. Selective excitation with a violet‐light‐emitting diode tu...

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Detalles Bibliográficos
Autores principales: Buzzetti, Luca, Prieto, Alexis, Roy, Sudipta Raha, Melchiorre, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5698711/
https://www.ncbi.nlm.nih.gov/pubmed/28984403
http://dx.doi.org/10.1002/anie.201709571