Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides

[Image: see text] Radical trifluoromethylation of aryl N,N-dimethyl hydrazones using TBAI as an initiator and Togni’s reagent as a trifluoromethyl radical source is described. Cascades proceed via electron-catalysis; this approach is generally more applicable to hydrazone perfluoroalkylation using p...

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Detalles Bibliográficos
Autores principales: Janhsen, Benjamin, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5698881/
https://www.ncbi.nlm.nih.gov/pubmed/28521099
http://dx.doi.org/10.1021/acs.joc.7b00934

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5698881/
https://www.ncbi.nlm.nih.gov/pubmed/28521099
http://dx.doi.org/10.1021/acs.joc.7b00934

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