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Hydrolysis, polarity, and conformational impact of C-terminal partially fluorinated ethyl esters in peptide models
Fluorinated moieties are highly valuable to chemists due to the sensitive NMR detectability of the (19)F nucleus. Fluorination of molecular scaffolds can also selectively influence a molecule’s polarity, conformational preferences and chemical reactivity, properties that can be exploited for various...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5704756/ https://www.ncbi.nlm.nih.gov/pubmed/29234471 http://dx.doi.org/10.3762/bjoc.13.241 |